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2021-08-28 00:00 瀏覽量 : 33<div class="bdsharebuttonbox bdsharebuttonboxz" style="width: 18%; margin: 0px auto;"><a href="#" class="bds_more" data-cmd="more"></a><a href="#" class="bds_qzone" data-cmd="qzone" title="分享到QQ空間"></a><a href="#" class="bds_tsina" data-cmd="tsina" title="分享到新浪微博"></a><a href="#" class="bds_tqq" data-cmd="tqq" title="分享到騰訊微博"></a><a href="#" class="bds_renren" data-cmd="renren" title="分享到人人網"></a><a href="#" class="bds_weixin" data-cmd="weixin" title="分享到微信"></a></div> <script>window._bd_share_config={"common":{"bdSnsKey":{},"bdText":"","bdMini":"2","bdMiniList":false,"bdPic":"","bdStyle":"1","bdSize":"16"},"share":{},"image":{"viewList":["qzone","tsina","tqq","renren","weixin"],"viewText":"分享到：","viewSize":"16"},"selectShare":{"bdContainerClass":null,"bdSelectMiniList":["qzone","tsina","tqq","renren","weixin"]}};with(document)0[(getElementsByTagName('head')[0]||body).appendChild(createElement('script')).src='http://bdimg.share.baidu.com/static/api/js/share.js?v=89860593.js?cdnversion='+~(-new Date()/36e5)];</script> </dt><dd class="more_img" style="overflow: hidden;"> <p> 聚丙烯酰胺家用,聚丙烯酰胺溶液的粘度主要反映液體分子間因流動或相對運動而產生的內摩擦阻力。內摩擦阻力與聚合物的結構、溶劑的性質、溶液的濃度、溫度和壓力等因素有關。它的值越大，溶液的粘度越大。<br/> 1、溫度對聚丙烯酰胺粘度的影響<br/>溫度是分子不規則熱運動強度的反映。分子的運動必須克服分子間的相互作用力，而分子間的相互作用，如分子間氫鍵、內摩擦、擴散、分子鏈取向、纏結等，直接影響粘度的大??小，所以粘度的大小聚合物溶液會隨溫度變化。溫度變化對聚合物溶液粘度的影響是顯著的。聚丙烯酰胺溶液的粘度度隨溫度升高而降低。原因是聚合物溶液的分散相顆粒相互纏結形成具有網絡結構的聚合物。溫度越高，網絡結構越容易被破壞，因此其粘度降低。<br/> 2、水解時間對聚丙烯酰胺粘度的影響<br/>聚丙烯酰胺溶液的粘度隨水解時間的延長而變化。水解時間短，粘度小。這可能是因為聚合物還沒有來得及形成網絡結構。 ;水解時間過長，粘度降低，這是由于溶液中聚丙烯酰胺的結構松散所致。部分水解的聚丙烯酰胺溶于水后分解成帶負電荷的大分子。分子間的靜電斥力和同一分子上不同鏈間的陰離子斥力，使分子在溶液中拉伸，使分子相互纏結。這就是部分水解聚丙烯酰胺可以顯著增加其溶液粘度的原因。聚丙烯酰胺家用</p><p> 3、鹽度對聚丙烯酰胺粘度的影響<br/>聚丙烯酰胺分子鏈中的陽離子基團比陰離子基團多，具有更多的凈電荷和更大的極性。 H2O是極性分子。根據相容相容原理，聚合物具有更好的水溶性和更大的特性粘度；隨著礦物含量的增加，正靜電荷部分被陰離子包圍，形成離子氣氛，從而與周圍的正靜電荷結合，聚合物溶液極性降低，粘度降低；礦物質濃度不斷增加，正負離子基團形成分子內或分子間氫鍵締合（導致聚合物在水中的溶解度降低），加入的鹽離子通過屏蔽正負電荷，解體正負離子結合，破壞形成的鹽鍵（導致聚合物在水中的溶解度增加）。這兩種作用相互競爭，使得聚合物溶液在較高溫度下的鹽濃度（>0.06 mol/L）下粘度保持較小。<br/> 4、分子量對聚丙烯酰胺粘度的影響<br/>聚丙烯酰胺溶液的粘度隨著聚合物分子量的增加而增加。這是因為聚合物溶液的粘度是由分子運動時分子間的相互作用產生的。當聚合物的相對分子量約為106時，聚合物線圈開始相互穿透，足以影響光的散射。當含量較高時，機械纏結足以影響粘度。當含量很低時，聚合物溶液可視為網絡結構，鏈間機械纏結和氫鍵共同形成網絡的節點。在更高的水平下，溶液包含許多鏈連接，使聚合物溶液呈凝膠狀。因此，聚合物的相對分子量越高，分子間越容易形成鏈纏結，溶液的粘度也越大。聚丙烯酰胺家用</p> </dd> </dl> <div class="page_c"> <a title=" 聚丙烯酸酯聚丙烯酰胺" href="http://www.yashikanews.com/a/jbxszjbxxa.html">上一篇：聚丙烯酸酯聚丙烯酰胺</a> <a title="聚丙烯酰胺原粉廠家" href="http://www.yashikanews.com/a/jbxxayfcj.html">下一篇：聚丙烯酰胺原粉廠家</a> </div> 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